Volcanoes Deliver Two Flavors of Water
But in volcanoes from the Manus Basin they also discovered evidence of seawater distilled long ago from a more ancient plate descent event, preserved for as long as 1 billion years. The data indicate that these ancient oceanic "slabs" can return to the upper mantle in some areas, and that rates of hydrogen exchange in the deep Earth may not conform to experiments.
The research is published in the February 26, 2012, advanced on line publication of Nature Geoscience.
As Carnegie coauthor Erik Hauri explained, "Hydrogen and boron have both light and heavy isotopes. Isotopes are atoms of the same element with different numbers of neutrons. The volcanoes in the Manus Basin are delivering a mixture of heavy and light isotopes that have been observed nowhere else. The mantle under the Manus Basin appears to contain a highly distilled ancient water that is mixing with modern seawater."
Lead author Alison Shaw and coauthor Mark Behn, both former Carnegie postdoctoral researchers, recognized another unique feature of the data. Lab experiments have shown very high diffusion rates for hydrogen isotopes, which move through the mantle as tiny protons. This diffusion should have long-ago erased the hydrogen isotope differences observed in the Manus Basin volcanoes.
"That is what we typically see at mid-ocean ridges," remarked Hauri. "But that is not what we found at Manus Basin. Instead we found a huge range in isotope abundances that indicates hydrogen diffusion in the deep Earth may not be analogous to what is observed in the lab."
The team's finding means is that surface water can be carried into the deep Earth by oceanic plates and be preserved for as long as 1 billion years. They also indicate that the hydrogen diffusion rates in the deep Earth appear to be much slower than experiments show. It further suggests that these ancient slabs may not only return to the upper mantle in areas like the Manus Basin, they may also come back up in hotspot volcanoes like Hawaii that are produced by mantle plumes.
The results are important to understanding how water is transferred and preserved in the mantle and how it and other chemicals are recycled to the surface.