Methane's Secrets, From Diamonds to Neptune
New research from a team led by Carnegie's Alexander Goncharov hones in on the hydrocarbon methane (CH4), which is one of the most abundant molecules in the universe. Despite its ubiquity, methane's behavior under the conditions found in planetary interiors is poorly understood due to contradictory information from various modeling studies. The work is published by Nature Communications.
Lead author Sergey Lobanov explains: "Our knowledge of physics and chemistry of volatiles inside planets is based mainly on observations of the fluxes at their surfaces. High-pressure, high-temperature experiments, which simulate conditions deep inside planets and provide detailed information about the physical state, chemical reactivity, and properties of the planetary materials, remain a big challenge for us."
For example, methane's melting behavior is known only below 70,000 times normal atmospheric pressure (7 GPa). The ability to observe it under much more extreme conditions is fundamental information for planetary models.
Using high-pressure experimental techniques, the team--including Carnegie's Lobanov, Xiao-Jia Chen, Chang-Sheng Zha, and Ho-Kwang "Dave" Mao--was able to examine methane's phases and reactivity under a range of temperatures and pressures mimicking environments found beneath Earth's surface.
At pressures reaching 790,000 times normal atmospheric pressure (80 GPa), methane's melting temperature is still below 1,900 degrees Fahrenheit. This suggests that methane is not a solid under any conditions met deep within most planets. What's more, its melting point is even lower than melting temperatures of water (H2O) and ammonia (NH3), other very important components in the interiors of giant planets.
These findings have implications both for Earth's deep chemistry and for the geochemistry of icy gas giant planets such as Uranus and Neptune. The team argues that this reactivity may play a role in the formation of ultradeep diamonds deep within the mantle. They assert that their findings should be taken into account in future models of the interiors of Neptune and Uranus, which are believed to have mantles consisting of a mixture of methane, water, and ammonia components.
Studying the interior of the Earth is important in understanding how physical processes affect the habitability of our planet. The chemistry and environment of the subsurface of our planet is also of interest as a habitat for unique forms of life that live deep below the ground, and possibly independent of energy from the Sun.
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