High Carb Heaven

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"… some warm little pond, with all sorts of ammonia and phosphoric salts, light, heat, electricity etc…", Charles Darwin, on the origins of life in tidal pools
Credit:Smithsonian

Astronomers using the National Science Foundation’s giant Robert C. Byrd Green Bank Telescope (GBT) have discovered a frigid reservoir of simple sugar molecules in a cloud of gas and dust some 26,000 light-years away, near the center of our Milky Way Galaxy. The discovery suggests how the molecular building blocks necessary for the creation of life could first form in interstellar space.

The astronomers detected the 8-atom sugar molecule glycolaldehyde in a gas-and-dust cloud called Sagittarius B2. Such clouds, often many light-years across, are the raw material from which new stars and planets are formed. The astronomers detected the same molecule in a warmer part of that cloud in 2000, but the new detection shows that the sugar exists at an extremely low temperature — only 8 degrees above absolute zero, the temperature at which all molecular motion stops. The cold glycolaldehyde detections were surprisingly strong when compared to the original detections and indicate that a considerable quantity of this simple interstellar sugar exists at extremely low temperatures.

Glycoaldehyde is composed of 2 carbon atoms, 2 oxygen atoms and 4 hydrogen atoms and is called a 2-carbon sugar. Glycolaldehyde can react with a 3-carbon sugar to produce a 5-carbon sugar called ribose. Ribose molecules form the backbone structure of the molecules DNA and RNA, which carry the genetic code of living organisms.

On Earth, most chemical reactions occur in liquid water. Conditions are quite different in interstellar space, and most of the complex molecules appear to form on or under the surfaces of tiny dust grains. In this scenario, smaller molecules such as water, formaldehyde, methane, ammonia, carbon dioxide, or methanol, coat the surfaces and interiors of dust grains in the clouds. When a shock wave, caused by the infall or outflow of material in the star-formation process, hits the dust grains, it provides the energy to assemble more-complex molecules from the simpler ones, and also to free the newly-formed molecules from the dust grains. Once the shock has passed, the molecules cool into a cold, thin gas.

orion
"We think that sugars are particularly important. And the reason for that is they don’t tend to form very well under acidic conditions. Yet they are needed for early life, and we think that early life formed under acidic conditions. So it might be helpful to life starting if the sugars were available early, and life only had to learn a little bit later how to make sugars. So we think it would be very interesting to find whether sugars are formed in space and whether they enter the solar system in comets. " Neville Woolf, Arizona
Credit: Weber State University

Although the chemistry on Earth and in interstellar clouds is much different, the results can be very similar. This and other recent studies show that prebiotic chemistry — the formation of the molecular building blocks necessary for the creation of life — occurs in interstellar clouds long before that cloud collapses to form a new solar system with planets. "Many of the interstellar molecules discovered to date are the same kinds detected in laboratory experiments specifically designed to synthesize prebiotic molecules. This fact suggests a universal prebiotic chemistry," said Jan M. Hollis of NASA’s Goddard Space Flight Center in Greenbelt, MD. This suggests that the molecular building blocks for the creation of life on a new planet might get a head start in the dust of interstellar clouds.

The actual formation of a planetary system is such a hot process that any prebiotic molecules would likely be destroyed. However, this study has shown that such molecules may form in very cold regions following the passage of a shock wave. Such conditions might be typical of the outer regions of a young solar system following the star-formation process. A repository of prebiotic molecules might exist in these outer regions, which is also where comets are formed, the scientists said. It has long been suggested that a collision with a comet or an encounter with the passing tail of a comet might "seed" a young planet with prebiotic material.

Hollis worked with Philip Jewell of the National Radio Astronomy Observatory in Green Bank, WV, Frank Lovas of the National Institute of Standards and Technology in Gaithersburg, MD, and Anthony Remijan of NASA’s Goddard Space Flight Center. The scientists reported their findings in the September 20 issue of the Astrophysical Journal Letters.

RNA
A 3D structure of RNA, a ribose sugar.
Credit: SpaceDaily

The discovery of the cold glycolaldehyde was made by detecting faint radio emission from the molecules. Molecules rotate end-for-end. When they change from a higher rotational energy level to a lower energy level, they emit radio waves at precise frequencies. Conversely, they can absorb radio waves at specific frequencies and change from a lower rotational energy level to a higher one. A set of frequencies emitted or absorbed by a particular molecule forms a unique "fingerprint" identifying that molecule. The cold glycolaldehyde was identified both by emission from the molecules and by absorption of radio waves emitted by a background source, all between 13 GHz and 22 GHz in frequency.

"The large diameter and great precision of the GBT made this discovery possible, and also holds the promise of discovering additional new complex interstellar molecules," Jewell said. The GBT, dedicated in 2000, is the world’s largest fully- steerable radio-telescope antenna. Its dish reflector has more than 2 acres of signal-collecting area.


The National Radio Astronomy Observatory is a facility of the National Science Foundation , operated under cooperative agreement by Associated Universities, Inc .

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